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Question

0.1 m urea solutions will have freezing point (Kf=1.86 K kg mol1):

A
273.093 K
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B
273.186 K
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C
272.907 K
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D
272.814 K
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Solution

The correct option is D 272.814 K
Depression in freezing point (ΔTb)=i×Kb×m

=1×1.86×0.1=0.186oC

Freezing point of Water =0oC

Freezing point of 0.1m urea

=0oC0.186=0.186oC=272.814K

option D is correct.

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