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Question

0.1 mol of methyl amine (Kb = 5 × 104) is mixed with 0.08 mol of HCl and the solution is diluted to 1 litre. The hydrogen ion concentration of the resulting solution is:


A

[H+] = 3.68 × 1011 M

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B

[H+] = 1.79 × 1011 M

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C

[H+] = 6.53 × 1011 M

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D

[H+] = 8 × 1011 M

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Solution

The correct option is D

[H+] = 8 × 1011 M


CH3NH2 + HCl CH3N+H3Cl

At start
0.1 mol 0.08 mol 0 mol

On completion
0.02 mol 0 mol 0.08 mol

pOH = pKb + log[salt][Base] = log(5 × 104) + log.08.02 = 3.9

So pH = 14 - 3.9 = 10.1

[H+] = 8 × 1011 M


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