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Question

0.115 g of a dibasic acid required 25 mlof 0.1NNaOHsolution for complete neutralisation. Calculate the molecular mass of acid

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Solution

25 ml of 0.1 N of NaOH = 0.115 g1000 ml of 0.1 N NaOH = 0.115 25 × 0.1 × 1000 × 0.1 =4.6 g1000 ml of 1 N acid = 4.60.1 × 1 = 46 gThus the equivalent mass = 46 gAcid is a dibasic acid so n=2Molecular mass of the acid = Eq mass × n = 46 × 2 = 92 g

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