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Question

0.124 g of iron wire was dissolved in dilute H2SO4 in oxygen free atmosphere and the resultant solution was titrated against 0.09672 N solution of KMnO4. The titre value was 22.90 mL. Calculate the percentage purity of iron wire.

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Solution

22.90 mL 0.09672 N KMnO422.90 mL 0.09672 N FeSO4
Amount of FeSO4 in the solution =0.09672×152×22.901000
=0.3366 g
Amount of iron in 0.3366 g of FeSO4=56152×0.3366
=0.124 g
Thus, percentage =0.1240.124×100=100
The iron wire is 100% pure.

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