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Question

0.250 g of an element M reacts with excess fluorine to produce 0.547 g of the hexafluoride, MF6. What is the element?
[Atomic mass of Cr=52 g, Mo=96 g, S=32 g, Te=127.6 g]

A
Cr
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B
Mo
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C
S
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D
Te
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Solution

The correct option is B Mo
M+3F2MF6

Let m be the molar mass of the element.

The molar mass of MF6 will be m+6×18.9=m+113.4 g/mol.

Thus, m g of the element M will give m+113.4 g of MF6.

Thus, 0.250 g of the element M will give 0.250m×(m+113.4) g of MF6 which is equal to 0.547 g.

Hence, 0.250m×(m+113.4)=0.547

0.250 m+28.35=0.547m

m=95.5 g/mol.

Hence, the element is Mo (with molar mass 96 g/mol).

Hence, the correct option is B

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