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Question

0.257 g of an organic substance was heated with conc. H2SO4 and then distilled with excess of strong alkali. The ammonia gas evolved was absorbed in 50 mL of M/10 HCl which required 23.2 mL of M/10 NaOH for neutralisation at the end of the process. Determine the percentage of nitrogen in the compound.

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Solution

Percentage of Nitrogen in compound
%N=1.4× Normality of HCl × volume of HCl used for complete Neutralization
Mass of organic substance
=1.4×0.1×23.20.257
%N=12.63

1117018_862628_ans_e4507b9a329a4f8b919c0d066464a42a.jpg

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