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Industrial Preparation of Ammonia

0.5 mole of F...

Question

0.5 mole of FeS is made to react with 49 H2SO4. The mass of H2S formed is FeS + H2SO4--H2S + FeSO4

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H_{2} S O_{4}

1

H_{2} S

K I

H_{2} S O_{4}

I_{2}

H_{2} S

K M n O_{4} + K I + H_{2} S O_{4} \to

K_{2} C r_{2} O_{7} + H_{2} S O_{4} + H_{2} S \to

K M n O_{4} + H_{2} S O_{4} + F e S O 4 \to

K I

H_{2} S O_{4}

I_{2}

H_{2} S

0.2 M H_{2} S O_{4}

0.1

H_{2} S

4

(H_{2})

64

44.8

O_{2}

H_{2} S O_{4}

49

H_{2} S O_{4}

%

Assertion : For drying $H_{2} S$ , Conc. $H_{2} S O_{4}$ cannot be used.

Reason: Moist $H_{2} S$ is oxidized by Conc. $H_{2} S O_{4}$

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