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Question

0.607 g of silver salt of a tribasic acid on combustion gave 0.37 g pure silver. Calculate the molecular weight of acid.

A
105.3
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B
110.6
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C
210.6
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D
220.12
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Solution

The correct option is B 210.6
Eq wt of silver salt = Eq. wt of silver
0.607E=0.37108

Eq.wt of silver salt = 177.2
M.wt of silver salt (tribasic)= 177.2 *3 = 531.6
M.wt of acid = 531.6 - 3 * At.wt of silver + 3* At.wt of H
= 531.6 -3 * 108 +3 * 1
= 210.6

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