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Question

0.61 g of an organic substance was heated in carius tube and the sulphuric acid formed was precipitated as BaSO4 with BaCl2. The weight of the dry BaSO4 was 0.53 g. Find the percentage of Sulphur.

A
11.90%
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B
43%
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C
23.04%
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D
51.2%
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Solution

The correct option is D 11.90%
Mass of organic compound = 0.61 g
Mass of = 0.53 g
Molar mass of = 233 g/mole
Molar mass of sulfur = 32 g/mol
First we have to calculate the mass of sulfur.
As 233 g of contains = 32 g of sulfur
So, 0.53 g of contains = 32233×0.53 = 0.072 of sulfur
Now we have to calculate the percentage of sulfur in an organic compound.
= 0.07261×100
= 11.90

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