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Question

0.72 gm of an oxide of a metal M on reduction with H2 gave 0.64 g of the metal. The atomic weight of the metal is 64. The empirical formula of the compound is:

A
MO
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B
M2O
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C
MO2
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D
M2O3
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Solution

The correct option is D M2O
According to the question, 0.72 g of the oxide contains 0.64 g metal

Since the atomic mass of the metal is 64, moles of metal=0.6464=0.01moles, and

moles of oxygen=0.720.6416=0.005moles

Hence, the ratio is 0.01:0.005=1:0.5=2:1

Hence empirical formula of the compound is M2O

Hence, option B is the correct answer.

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