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Question

1.0 k-mol of a sample of helium gas is put through the cycle of operations shown in figure. BC is an isothermal process and PA=1.00atm,VA=22.4m3,PB=2.00atm. What are TA,TBandVC ?
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Solution

Given : PA=1atm VA=22.4m3=22.4×103 L PB=2atm n=1000

Using ideal gas equation at A, PAVA=nRTA
1×22.4×103=1000×0.0821×TA TA=273K

Process AB : VA=VB
PAPB=TATB

12=273TB TB=546K
As the process BC is isothermal, thus TC=TB=546K

Process AC : Pressure is constant VCVA=TCTA
VC22.4=546273 VC=44.8m3

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