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Standard XII
Chemistry
Bromine Water Test
1, 3-Butadien...
Question
1, 3-Butadiene with bromine in molar ratio generates predominantly:
A
1,1 dibromo-2- butene
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B
1,4 dibromo-2- butene
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C
1,2 dibromo-2-butene
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D
1,3 dibromo-2-butene
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Solution
The correct option is
B
1,4 dibromo-2- butene
C
H
2
=
C
H
−
C
H
=
C
H
2
+
B
r
2
→
B
r
C
H
2
C
H
B
r
C
H
=
C
H
2
+
B
r
C
H
2
C
H
=
C
H
C
H
2
B
r
3,4-dibromo-1-butene 1,4-dibromo-2-butene
1,4-dibromo-2-butene is more predominant due to a resonance structure stabilizes the intermediate formed during the reaction.
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