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Question

1, 3-Butadiene with bromine in molar ratio generates predominantly:

A
1,1 dibromo-2- butene
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B
1,4 dibromo-2- butene
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C
1,2 dibromo-2-butene
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D
1,3 dibromo-2-butene
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Solution

The correct option is B 1,4 dibromo-2- butene
CH2=CHCH=CH2+Br2BrCH2CHBrCH=CH2+BrCH2CH=CHCH2Br
3,4-dibromo-1-butene 1,4-dibromo-2-butene

1,4-dibromo-2-butene is more predominant due to a resonance structure stabilizes the intermediate formed during the reaction.

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