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Question

1 A of current flowing through a silver voltameter for 25 minutes deposits 1.5 gm of silver. The e.c.e of silver will be (in gmC−1)

A
0.0001
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B
0.001
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C
0.01
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D
0.1
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Solution

The correct option is D 0.001
Given : t=25 minutes =1500 s W=1.5 gm I=1A
Using W=ZIt where Z is electrochemical equivalent (e.c.e)
1.5=Z×1×1500 Z=0.001 gm/C

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