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Question

1% aqueous solution of Ca(NO3)2 has freezing point:

A
0oC
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B
less than 0oC
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C
1oC
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D
2oC
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Solution

The correct option is B less than 0oC
The freezing point depression can be calculated by a formula
ΔTf=iKfb
ΔTf=TofTf= the depression of freezing point.
i= the van't hoff factor =3
Kf= Molar freezing depression constant = 1.86kg/mol
b= molar concentration of the solution = 0.062 mol/kg
δTf=3×1.86×0.062=0.34oC
Tf=Tof0.34o=0.34o

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