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Byju's Answer
Standard XII
Chemistry
Physical Properties of Alkenes
1-bromo butan...
Question
1-bromo butane on reaction with alcoholic KOH gives:
A
1-Butene
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B
1-Butanol
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C
2-Butene
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D
2-Butanol
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Solution
The correct option is
A
1-Butene
Reaction:
C
H
2
B
r
−
C
H
2
−
C
H
2
−
C
H
3
A
l
c
.
K
O
H
−
−−−−−
→
C
H
2
=
C
H
−
C
H
2
−
C
H
3
When 1-bromo butane reacts in the presence of alcoholic KOH, then it undergoes dehydrohalogenation to form 1-Butene as a product.
So, the correct option is
A
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1
Similar questions
Q.
Assertion :2-Butanol on heating with
H
2
S
O
4
gives 1-butene and 2-butene. Reason: Dehydration of 2-butanol follows Saytzeff rule.
Q.
A mixture of two alcohols
3
−
methyl
−
1
−
butanol and
2
−
methyl
−
1
−
butanol, given chiefly
2
−
methyl
−
2
−
butene when dehydrated with acid.
2
−
methyl
−
2
−
butene is converted into
2
−
methyl
−
2
−
butanol with approximately 90% yield by treatment with 50% aqueous solution of sulphuric acid at
0
∘
C. Write equation showing mechanism of conversions.
Q.
1
−
B
u
t
e
n
e
+
H
B
r
H
2
O
2
−
−−
→
h
ν
1
−
B
r
o
m
o
B
u
t
a
n
e
The above reaction follows:
Q.
Assertion :Treatment of
3
-methyl-
1
-butene with
H
g
(
C
H
3
C
O
O
)
2
−
H
2
O
followed by reduction with
N
a
B
H
4
gives
2
-methyl-
2
-butanol. Reason: The reaction proceeds through a cyclic mercurinium ion reactive intermediate.
Q.
1,3 Butadiene on reaction with HBr/water gives primarily 1-bromo-2-butene at high temperatures.
Give the reaction.
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