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Question

1 L of CO2 is passed over red hot coke. The volume becomes 1.4 L. The composition of the product(s) is:

A
0.6 L CO
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B
0.8 L CO2
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C
0.6 L CO2 and 0.8 L CO
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D
0.8 L CO2 and 0.6 L of CO
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Solution

The correct option is C 0.6 L CO2 and 0.8 L CO
Red hot coke reduces CO2 to CO. The balanced equation is CO2+C2CO.

1 mol of CO2 will give 2 mol of CO.

x L of CO2 will give 2x L of CO.

In the question, 1 L of CO2 will react to give 1.4 L of mixture.
Out of 1 L, x L of CO2 reacts. The unreacted quantity is 1x.

Total volume of mixture = unreacted CO2 + volume of CO formed.

Total volume of mixture =1x+2x=1.4 L.

Hence, x=0.4 L.

Thus, volume of CO formed = 2×0.4 L =0.8 L.

Volume of CO2 left = (10.4)L=0.6 L.

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