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Question

1 mol of MnO24 in neutral aqueous medium disproportionates to :

A
23 mol of MnO4 and 13 mol of MnO2
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B
13 mol of MnO4 and 23 mol of MnO2
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C
13 mol of Mn2O7 and 23 mol of MnO2
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D
23 mol of Mn2O7 and 13 mol of MnO2
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Solution

The correct option is A 23 mol of MnO4 and 13 mol of MnO2
In neutral medium, K2MnO4 (potassium mangnanate) disproportionate as follows:
K2MnO4KMnO4+MnO2
On balancing, we get
3MnO24+2H2O2MnO4+4OH+MnO2
1 mol MnO2423 mol MnO4=13 mol MnO2

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