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Question

1 mole each of H2(g) and I2(g) are introduced in a 1 L eacuated vessel at 523 K and equilibrium
H2(g)+I2(g)2HI(g) is established. The concentration of HI(g) at equilibrium:

A
Change on changing pressure
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B
Changes on changing temperature
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C
Change on changing volume of the vessel
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D
Is same even if only 2 mol of HI(g) were introduced in the vessel in the beginning
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Solution

The correct option is C Change on changing volume of the vessel
H2(g)+I2(g)2HI(g)
(a) For changing pressure, volume has to be changed, thouged, though number of moles of HI(g) do not get changed but its concentration will get changed.
(b) Temperature change will change Kp and hence concentration.
(C) Volume change will change concentration not the number of moles.
(D) Equilibrium concentration of the reactants and product depends upon the initial concentration and the equlibrium constant.

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