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Question

1 mole of A (g) is heated to 300C in closed one litre vessel till the following equilibrium is reached: A(g)B(g). The equilibrium constant for the reaction at 300C is 4. What is the concentration of B (in mol.lit1) at equilibrium?

A
0.2
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B
0.6
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C
0.8
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D
0.1
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Solution

The correct option is D 0.8
Initial concentration of A is 1 M. Let x represents the concentration of B in the equilibrium mixture. The concentration of A in the equilibrium mixture will be 1x. The expression for the equilibrium constant is K=BA.
Substitute values in the above expression.
4=x1x.
Hence, x=0.8.

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