1 mole of a gas AB3 present in 10L container dissociates into AB2(g) and B2(g). 2AB3(g)⇌2AB2(g)+B2(g)
If the degree of dissociation of AB3 is 80%, then final pressure at 600K is:
(Given R=0.082L atm K−1mol−1)
A
5.88atm
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B
1.25atm
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C
10.25atm
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D
6.88atm
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Solution
The correct option is D6.88atm 2AB3(g)⇌2AB2(g)+B2t=00.100t=eq0.1−0.080.080.04
Total number of moles per litre (nV)=0.14mol L−1
The final pressure at 600K is P=nV×R×T=0.14×0.082×600=6.88atm