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Question

10.0 mL of Na2CO3 solution is titrated against 0.2 M HCl solution. The following litre values were obtained in 5 readings 4.8 mL, 4.9 mL, 5.0 mL, 5.0 mL and 5.0 mL. Based on these readings and the convention of titrimetric estimation the concentration of Na2CO3 solution is ______mM


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Solution

Answer: 50

From reading values we can conclude that 5 mL of 0.2 M HCl solution is required to neutralise 10 mL of the given Na2CO3 solution.
Thus,

Equivalence of Na2CO3=Equivalence of HCl

M×10×nfactor(Na2CO3)=0.2×5×nfactor(HCl)
M×10×2=0.2×5×1
M=5×102M=50×103M=50mM

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