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Question

10 g glucose (molar mass 180) and 20 g of sucrose (molar mass 342) are dissolved in 100 g of water. What will be the vapour pressure of the resultant solution if the vapour pressure of water is 35 mm Hg?

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Solution

Mass of glucose = 10 g
No. of moles of glucose = 0.0556
Mass of sucrose = 20 g
No. of moles of sucrose = 0.0585
Mass of water = 100 g
No. of moles of water = 5.556
Total number of moles = 5.556+0.0585+0.0556
=5.67
Mole fraction of water =5.5565.67
Vapour pressure of solution = Mole fraction of water ×P0
=5.5565.67×35=34.3mmHg

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