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Question

10 g of cane sugar (molecular mass = 342) in 1×103m3 of solution produces an osmotic pressure of 6.68×104Nm2 at 273 K. Calculate the value of R in SI units.

A
8.3684JK1mol1
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B
9.3684JK1mol1
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C
7.3684JK1mol1
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D
5.3684JK1mol1
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Solution

The correct option is A 8.3684JK1mol1
Given data:
V=0.001 m3=1L,π=6.68×104Nm2,T=273K,w=10g,M.W.=342gmol1

We know that Osmotic pressure is-
π=iCRT
since, i=1 for cane sugar
π=CRT
6.68×104=10342R×273
We get-
R=8.36JK1mol1

Hence, option (A) is correct.

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