10 ml of 1M Bacl2 solution and 5ml 0.5 M K2SO4 are mixed together to precipitate out BaS04 .The amount of BaSO4 precipited will be
a) 0.005.mol b) 0.00025mol
c)0.025mol. c)0.0025 mol
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Solution
Volume in litres x molarity = number of moles Therefore, Number of moles of BaCl2 = 0.01 x 1 = 0.01 Number of moles of K2(SO4) = 0.005 x 0.5 = 0.0025 Reaction between BaCl2 and K2(SO4) : BaCl2 + k2(SO4) →BaSO4 + 2kCl According to the equation: 1 moles of BaCl2 give 1 moles of BaSO4 0.0025 moles of BaCl2 will give 0.0025 moles of BaSO4
Now, Molar mass of BaSO4 = 137g + 32g + 4 x 16 g = 233 g/mol Mass of 0.0025 moles of BaSO4 = 0.0025 x 233 = 0.5825 g