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Laboratory Preparation of Ammonia

10.Which of t...

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10.Which of the following statement is correct? 1-In the formation of dioxygen from atoms 10 molecular orbitals will be formed. 2-All the molecular orbitals in the dioxygen will be completely filled. 3-Total number of bonding molecular orbitals will not be same as total number of anti bonding orbitals in dioxygen. 4-Number of filled bonding orbitals will be same as number of filled anti bonding orbitals.

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Q. According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic orbitals through LCAO (linear combination of atomic orbitals). The correct statement (s) about molecular orbitals is/are Statement (a) : bonding molecular orbitals are formed by addition of wave-functions of atomic orbitals of same phase Statement (b) : anti-bonding molecular orbitals do not take part in bond formation because they belong to inner shells Statement (d) : anti-bonding molecular orbitals provide stability to molecules while bonding molecular orbitals make the molecules unstable.

Q. If the total energy of the two atomic orbitals is

x

and the energy difference between bonding and antibonding molecular orbitals is

y

then the energy of bonding and anti-bonding molecular orbital will be:

Which of the following will result in Anti-bonding Molecular Orbitals?

Q. According to VBT any covalent bond will be formed by overlapping of valence atomic orbitals of bonded atoms provided atomic orbitals must be half–filled and electrons be in opposite spin.
According to type of overlapping covalent bonds can be classified as: (a)

σ

π

δ

bond.
The combination of orbital that cannot produce non–bonding molecular orbital is:
(internuclear axis is z–axis)

Q. What is meant by bonding and anti-bonding molecular orbitals? Give number of electron which occupy bonding orbital in

H_{2}^{+}, H_{2} a n d H e_{2}

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