100ml0.1MH2O2 is mixed with 400ml0.5MH2O2. The volume of 0.1MKMnO4 (acidic) required to react with H2O2 mixture is :
A
840 ml
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B
420 ml
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C
630 ml
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D
None of these
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Solution
The correct option is A 840 ml FinalmilimolesofH2O2solution =(100)(0.1)+(0.5)(400)=210m.mol Now, mili.eq.(H2O2)=mili.eq.(KMnO4) ⇒(210)(2)=(V)(0.1)(5) ⇒V=840ml