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Question

100 ml of liquid A and 50 ml of liquid B are mixed to form 138 ml of solution. It is :

A
Ideal solution
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B
High boiling azeotrope
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C
Low boiling azeotrope
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D
None of these
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Solution

The correct option is B High boiling azeotrope
Volume of A=100 ml ; Volume of B=50 ml.

Ideal solution =100+50=150 ml
Non ideal =138 ml

ΔVmix=138150=12<0

This condition occurs when the vapour pressure of the solution is lesser then it should be.
Since the vapour pressure of the solution is lesser, therefore, the solution boils at a higher temperature.

Hence, option B is correct.

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