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Byju's Answer
Standard XII
Chemistry
Azeotropic Mixtures
100 ml of liq...
Question
100 ml of liquid A and 50 ml of liquid B are mixed to form 138 ml of solution. It is :
A
Ideal solution
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B
High boiling azeotrope
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C
Low boiling azeotrope
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D
None of these
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Solution
The correct option is
B
High boiling azeotrope
Volume of
A
=
100
m
l
; Volume of
B
=
50
m
l
.
Ideal solution
=
100
+
50
=
150
m
l
Non ideal
=
138
m
l
Δ
V
m
i
x
=
138
−
150
=
−
12
<
0
This condition occurs when the vapour pressure of the solution is lesser then it should be.
Since the vapour pressure of the solution is lesser, therefore, the solution boils at a higher temperature.
Hence, option B is correct.
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0
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′
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[Divide your answer by
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