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Question

100 ml of nitrogen at 0.30 atm, pressure and 50 ml of carbon dioxide at 0.60 atm. pressure are introduced into a vessel of volume 150 ml without any change in temperature. What will be ratio of the partial pressure of nitrogen to carbon dioxide in the vessel?

A
1:2
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B
2:1
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C
1:1
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D
1:3
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Solution

The correct option is C 1:1
The ratio of the partial pressure of nitrogen to carbon dioxide in the vessel will be equal to the ratio of the number of nitrogen to carbon dioxide. It will be equal to the ratio of the product of the pressure and volume of nitrogen to carbon dioxide .
Pnitrogen:Pcarbon dioxide=Ponitrogen×Vonitrogen:Pocarbon dioxide×Vocarbon dioxide= 0.30 atm×100 mL:0.60 atm×50 mL=1:1
Note: Pnitrogen and Pcarbon dioxide are final pressures.
Ponitrogen and Pocarbon dioxide are initial pressures.
Vonitrogen and Vocarbon dioxide are initial volumes.

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