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Question

100 ml of PH3 on heating forms P and H2. The volume change in the reaction is.

A
An increase of 50 ml
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B
An increase of 100 ml
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C
An increase of 150 ml
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D
An decrease of 50 ml
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Solution

The correct option is A An increase of 50 ml
2PH3(g)2P(s)+3H2(g)
2 ml 3 ml
2 ml of PH3 on decomposition gives 3 ml of H2, i.e., increase = 1 ml
100 ml of PH3 will result in increase = 50 ml

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