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Byju's Answer
Standard XII
Chemistry
Phosphine
100 ml of P...
Question
100
m
l
of
P
H
3
when decomposed produces phosphorus and hydrogen. The change in volume is:
A
50
m
l
increase
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B
500
m
l
decrease
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C
900
m
l
decrease
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D
none of the above
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Solution
The correct option is
A
50
m
l
increase
The equation for the decomposition is:
4
P
H
3
(
g
)
→
P
4
(
s
)
+
6
H
2
(
g
)
(Elemental phosphorus exists as tetra-atomic molecules).
When the temperature and pressure remain the same, 4 ml of
P
H
3
will give 6 ml of
H
2
. (On applying Gay-Lussac's law ).
Hence, 100 ml of
P
H
3
will yield 150 ml of
H
2
.
Increase in volume = (150-100) ml = 50 ml. (The volume of solid phosphorus is negligible).
Hence, the correct option is
A
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