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Question

100 cm3 of a 0.1 M HCl solution is mixed with 100 cm3 of a 0.2 N NaOH solution. The concentration of excess reagent left and the nature of resulting solution is:

A
Molarity = 0.1 M and the solution is basic
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B
Molarity = 0.1 M and the solution is acidic
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C
Molarity = 0.05 M and the solution is basic
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D
Molarity = 0.05 M and the solution is acidic
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Solution

The correct option is C Molarity = 0.05 M and the solution is basic
Molarity=number of moles of solutevolume of solution in mL×1000

Number of moles of HCl=100×0.11000=0.01

Number of moles of NaOH=100×0.21000=0.02

Since the moles of base are greater, the solution will be basic.
Moles of NaOH left after neutralization
=0.020.01=0.01
Molarity of NaOH in the resultant solution
=0.01200×1000=0.05 M

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