12. which of the following is isostructural? XeF2,IF2- NH3,BF3 CO32- , SO32- PCl5,ICl5? and, how?

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N O_{3}^{-}, C O_{3}^{2 -}, C l O_{3}^{2 -}, S O_{3}

Which of the following, are isoelectronic and isostructural ?

$N O_{3}^{-}, C O_{3}^{2 -}, C l O_{3}^{-}, S O_{3}$

B F_{3}, S F_{4}, N C l_{3}, P C l_{5}, S i F_{4}, B r F_{5}, X e F_{2}, B e C l_{2}

N O_{3}^{-}, C O_{3}^{2 -}, C l O_{3}^{-}, {S O}_{3}

Question 01

Isostructural species are those which have the same shape and hybridisation. Among the given species identify the isostructural pairs.

(a) $[N F_{3} a n d B F_{3}]$

(b) $[B F_{4}^{-} a n d N H_{4}^{+}]$

(d) $[N H_{3} a n d N O_{3}^{-}]$

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