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General Mechanism of Electrophilic Aromatic Substitution

14. Is odd el...

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14. Is odd electron counted in hybridisation like in free radicals or in NO2 type of species??

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Q. In which of the following species only one type of hybridisation is present?

Q. The species having

s p^{3}

hybridisation of atomic orbitals of nitrogen is/are

N O_{2}^{+}, N O_{3}^{-} a n d N H_{4}^{+}, N F_{3}

Q. In which radical odd electron is in pure orbital

N O_{2}

C l O_{2}

C H_{3}

C F_{3}

Q. Assertion :On cooling, the brown colour of

N O_{2}

disappears. Reason: On cooling

N O_{2}

(N_{2} O_{4})

resulting in the pairing of the odd electrons in

N O_{2}

.

Q. Attacking or reactive or electrophilic species in nitration of benzene is or in the nitration of benzene with concentrated

H N O_{3}

H_{2} S O_{4}

the attack on the ring is made by

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General Mechanism of Electrophilic Aromatic Substitution

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