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Question

16 moles of H2 and 4 moles of N2 are sealed in an one litre vessel. The vessel is heated at a constant temperature until the equilibrium is established, it is found that the pressure in the vessel has fallen to 9/10 th of its original value. Calculate new concentration of N2 and NH3 in mol L1
N2(g)+3H2(g)2NH3(g)

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Solution

The given equilibrium is
N2(g)+3H2(g)2NH3(g)At t=04160At equilibrium4x163x 2x
Total gaseous moles at equilibrium =4x+163x+2x=(202x)
Since, pressure has fallen to 9/10 of its original value, hence no. of mole will also fall up to the same extent.
(202x)=910×20=18
x=1
[N2]=4x1=411=3mole/litre
[NH3]=2x1=2 mole/litre

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