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Standard XII
Chemistry
Solublity
16. The ratio...
Question
16. The ratio of d values in NaCl crystal is 1:0.707:1.154 how these values are obtained?
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Q.
A student obtained the values of cohesive energy for four types of crystals as
764
,
447
,
108
and
7.74
k
J
/
m
o
l
respectively. If the crystals used by him are Ar, Na, Si and
N
a
C
l
, then the correct correlation is :
Q.
Which is the minimum values of
r
+
/
r
−
needed to prevent anion-anion contact in
N
a
C
l
crystals?
Q.
In NaCl crystal, the radius ratio is:
Q.
The experimental values of colligative properties of many solutes in solution resembles calculated values of colligative properties.
However in some cases, the experimental values of colligative properties differ widely than those obtained by calculations. Such experimental values of colligative properties are known as abnormal values of colligative properties. The causes for abnormal values of colligative properties are:
(i) Dissociation of solute: It increases the colligative properties.
e.g.: Dissociation of
KCl, NaCl
etc. in
H
2
O
.
(ii) Association of solute: It decreases the colligative properties.
e.g.: Dimerisation of acetic acid in benzene.
Four different
100
ml
solutions are prepared by mixing 1 gram each of
N
a
C
l
,
(
N
H
2
)
2
C
O
,
N
a
2
S
O
4
and
K
4
[
F
e
(
C
N
)
6
]
at a temperature T. Correct order of osmotic pressure is:
Q.
An unbiased coin is tossed
5
times. Suppose that a variable
X
is assigned the value
k
when
k
consecutive heads are obtained for
k
=
3
,
4
,
5
, otherwise
X
takes the value
−
1
. The expected value of
X
, is
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