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Question

18.0 g of water completely vaporises at 100C and 1 bar pressure and the enthalpy change in the process is 40.79 kJ mol1. What will be the enthalpy change for vaporising two moles of water under the same conditions? What is the standard enthalpy of vaporisation for water?

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Solution

Given that, quantity of water =18.0 g, pressure =1 bar
As we know that, 18.0 gH2O = 1 mole H2O
Enthalpy change for vaporising 1 mole of H2O = 40.79 kJ mo11
Enthalpy change for vaporising 2 moles of H2O = 2 × 40.79 kJ= 81.358kJ
Standard enthalpy of vaporisation at 100C and 1 bar pressure, ΔvapH=+40.79 kJ mol1


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