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Standard X
Chemistry
Covalent Bond
19. 1,3 dibro...
Question
19. 1,3 dibromo-propane react with zinc to give- (a)propene (b)propane (c)cyclopropane (d)hexane
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Q.
Consider the following two reactions:
(i) Propene +
H
2
→
Propane;
Δ
H
1
(ii) Cyclopropane +
H
2
→
Propane;
Δ
H
2
Then,
|
Δ
H
2
-
Δ
H
1
|
will be:
Q.
Consider the following two reactions:
(i)
P
r
o
p
e
n
e
+
H
2
⟶
p
r
o
p
a
n
e
;
Δ
H
1
(ii)
C
y
c
l
o
p
r
o
p
a
n
e
+
H
2
⟶
P
o
r
p
a
n
e
;
Δ
H
2
then
Δ
H
2
−
Δ
H
1
will be:
Q.
Assertion :Addition of
H
B
r
in presence of peroxide
(
R
O
O
R
)
to propene gives
2
-bromo propane. Reason: Reaction involves a bromine-free radical.
Q.
Photobromination of 2-methyl propane gives a mixture of 1-bromo-2-methyl propane and 2-bromo-2-methyl propane in the ratio:
Q.
From the following data, calculate the enthalpy change for the combustion of cyclopropane at 298 K. The enthalpy of formation of
C
O
2
(
g
)
,
H
2
O
(
l
)
and propane (g) are -393.5, -285.8 & 20.42 kJ/mol respectively. The enthalpy of isomerisation of cyclopropane to propene is -33.0 kJ/mol.
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