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Question

1L flask contains nitrogen along with a drop or two of water at 40C, the total pressure being 760 torr. If all the conents are transferred to another flask of 0.5 L at the same temperature, the pressure set up in the second flask will be (aqueous tension at 40C=55 torr)


A

1410 torr

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B

1465 torr

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C

1520 torr

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D

None of these

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Solution

The correct option is B

1465 torr


P1(dry)×V1=P2(dry)×V2;P1=Pwetaqueous tension=76055=705 torr
V2=0.5L, Hence, P2 (dry gas) =705×10.5=1410 torr
P2 (Wet gas) =1410+55=1465 torr


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