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Question

2.16 grams of Cu, on reaction with HNO3, followed by ignition of the nitrate, gave 2.7 g of copper oxide. In another experiment 1.15 g of copper oxide, upon reaction with hydrogen, gave 0.92 g of copper. This data illustrate the law of:

A
multiple proportions
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B
definite proportions
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C
reciprocal proportions
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D
conservation of mass
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Solution

The correct option is B definite proportions
In the first sample of copper oxide (obtained by the action of nitric acid on Cu), the mass of Cu is 2.16 g and the mass of oxygen is 2.72.16=0.54 g.
The ratio of the mass of Cu to the mass of oxygen is 2.160.54=4:1
In the second sample of copper oxide (which reacts with hydrogen) , the mass of Cu is 0.92 g and the mass of oxygen is 1.150.92=0.23 g.
The ratio of the mass of Cu to the mass of oxygen is 0.920.23=4:1
Hence, this illustrates the law of definite Proportions.

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