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Question

2.8×102 kg of nitrogen is expanded isothermally and reversibly at 300 K from 15.15×105Nm2 when the work done is found to be -17.33 kJ. Find the final pressure.

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Solution

W=2.303nRTlog(P1P2)

17.33kJ=2.303×WM×RTlogP1p2

17.33×103=2.303×2.8×102×10328×8.314×300×log15.15×105P2

17.33×103=2.303×2.8×102×10328×8.314×300×(log15.15×105l0gP2)

(log15.15×105logP2)=17.33×103×282.303×2.8×10×8.314×300

(6.18logP2)=3.017

logP2=6.183.017=3.163

P2=antilog (3.163)

P2=1455.46N/m2

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