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Question

2-Bromo-3-phenylpropane can be synthesized by:

A
C6H5CH2CH(OH)CH3+PBr3
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B
C6H5CH=CHCH3+HBr+benzoylperoxide
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C
C6H5CH2CH2CH3+Br2+light
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D
none of these
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Solution

The correct options are
A C6H5CH2CH(OH)CH3+PBr3
C C6H5CH=CHCH3+HBr+benzoylperoxide
2-Bromo-3-phenylpropane can be synthesized by reactions A and
B. In reaction A, -OH group is replaced with Br.
(A) C6H5CH2CH(OH)CH3+PBr3C6H5CH2CH(Br)CH3
In the reaction B, a molecule of HBr is added across C=C bond.
(B) C6H5CH=CHCH3+HBr+benzoylperoxideC6H5CH2CH(Br)CH3
In the reaction C, 1-Bromo-1-phenylpropane is obtained.
(C) C6H5CH2CH2CH3+Br2+lightC6H5CHBrCH2CH3

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