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Question

2Chlorobutane15% aq. solution of ethyl alcohol−−−−−−−−−−−−−−−−−−P

In this reaction 70% racemisation takes place. % of inverted product would be:

A
30
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B
70
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C
35
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D
65
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Solution

The correct option is D 65
2Chlorobutane15% aq. solution of ethyl alcohol−−−−−−−−−−−−−−−−−−SN1+SN2
SN130>20>10
SN210>20>30

In SN1 reaction racemic mixture (Retension+Inversion) and in SN2 reaction inverted product are produced.

So inverted product is = 100% - 70%
= 30%
Total inverted product = 35%+30%= 65%

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