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Question

2 electron 3 atom bonds are formed in diborane between hydrogen and boron.
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Solution

Answer 1
A three-center two-electron bond is an electron-deficient chemical bond where three atoms share two electrons. Diborane B2H6 structure containing four terminal and two bridging hydrogen atoms. The model determined by molecular orbital theory indicates that the bonds between boron and the terminal hydrogen atoms are conventional 2-center, 2-electron covalent bonds. The bridging hydrogen atoms provide one electron each. Thus the B2H2 ring is held together by four electrons, an example of 3-center 2-electron bonding. This type of bond is sometimes called a 'banana bond'.

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