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Question

2 litres of NH3 at 300C and at 0.20 atm is neutralised by 134 mL of a solution of H2SO4. The normality of H2SO4 is (in multiples of 100)

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Solution

Given for NH3: V=2 L, T=303 K, P=0.20 atm.

PV=wmRT

wm or moles of NH3=PVRT =(0.2×2)(0.082×303)=0.01609

NH3 is monoacidic base.
Moles of NH3=Equivalent of NH3=0.01609
Meq. of NH3=16.09
Meq. of H2SO4= Meq. of NH3
N×134=16.09
Therefore, normality of H2SO4=0.12 N
So, the answer is 12.

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