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Question

2-Methyl propane on monochlorination under photochemical condition give:

A
2-chloro-2-methylpropane as major product
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B
(1:1) mixture of 1-chloro-2-methylpropane and 2-chloro-2-methylpropane
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C
1-chloro-2-methylpropane as a major product
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D
(1:9) mixture of 1-chloro-2-methylpropane
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Solution

The correct option is A 2-chloro-2-methylpropane as major product
2-chloro-2-methyl-propane.
This reaction occur via radical mechanism.

1158380_1042931_ans_fc6cbe13756042d385ec50622984c916.PNG

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