2g of acetate ions in the form of sodium acetate are added to 500mL of a 0.10Macetic acid solution of pKa(CH3COOH)=4.74. What is the pH of the final solution?
A
4.56
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B
4.74
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C
5.01
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D
5.70
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Solution
The correct option is A4.56 No of mmoles of acetate ion =2×100060=33.33mmoles also, 50 mmoles of CH3COOH are present in the solution. pH=pKa+log[CH3COO−]CH3COOH] pH=4.74+log33.3350 pH=4.74+log2−log3=4.564