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Byju's Answer
Standard XII
Chemistry
Heat of Reaction
20
Question
20
% decomposition of
H
2
O
2
in the presence of acid requires
5
min. The time required for
50
% decomposition in minutes is:
A
15.52
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B
1.552
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C
0.1552
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D
7.76
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Solution
The correct option is
A
15.52
For a first order reaction,
k
=
2.303
t
l
o
g
a
a
−
x
k
=
2.303
5
l
o
g
100
80
=
0.044637
But the half life period
t
1
/
2
=
0.693
k
=
0.693
0.044637
=
15.52
m
i
n
.
Option A is correct.
Suggest Corrections
0
Similar questions
Q.
At
380
o
C
, the half-life period for the first order decomposition of
H
2
O
2
is 360 min. The energy of activation of the reaction is
200
k
J
m
o
l
−
1
. The time required for 25% decomposition at
450
o
C
in minutes (nearest integer) is :
Q.
At
380
∘
C, the half-life period for the first-order decomposition of
H
2
O
2
is 360 min. The energy of activation of the reaction is 200 kJ mol
−
1
. Calculate the time required for 75% decomposition at
450
∘
C
?
Q.
The decomposition of
H
2
O
2
is studied by volumetric measurement of the concentration of
H
2
O
2
by
K
M
n
O
4
solution at different intervals of time.
(
H
2
O
2
→
H
2
O
+
1
2
O
2
)
If 5 ml of
H
2
O
2
required 10 mL of 0.1 N
K
M
n
4
at the start of the reaction and after 10 min, 5 mL of
H
2
O
2
required 5 Ml of 0.1
K
M
n
O
4
. The rate constant k of
−
d
[
H
2
O
2
]
d
t
=
k
[
H
2
O
2
]
is_________. (
i
n
m
i
n
−
1
)
Q.
Decomposition of
H
2
O
2
is prevented in presence of
:
Q.
The time required for
15
% decomposition at an initial conc. of
0.1
M
in a first order reaction
A
→
P
r
o
d
u
c
t
s
, at
80
∘
C
is
25
m
i
n
, then the time required for decomposition by
0.06
M
at an initial conc. of
0.4
M
at
353
K
is:
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