200 mL of a N10H2SO4 solution is mixed with 300 mL of a N100NaOH solution. Calculate the normality of the excess H+/OH− ions in the resulting solution.
A
0.024N
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B
0.015N
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C
0.050N
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D
0.034N
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Solution
The correct option is D0.034N Number of gram equivalents of H2SO4= Normality × Volume in L =0.1×0.2=0.02
Number of gram equivalents of NaOH = Normality × Volume in L =0.01×0.3=0.003
0.003 gram equivalents of NaOH will neutralize 0.003 gram equivalents of H2SO4.
Hence, the number of gram equivalents of H2SO4 in 500 mL of the solution after neutralisation = 0.02 - 0.003
= 0.017
Hence, the number of gram equivalents of H+= 0.017 Normality of H+=Number of gram equivalentsVolume of solution in L