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Question

200 mL of a N10 H2SO4 solution is mixed with 300 mL of a N100 NaOH solution. Calculate the normality of the excess H+/OH ions in the resulting solution.

A
0.024 N
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B
0.015 N
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C
0.050 N
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D
0.034 N
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Solution

The correct option is D 0.034 N
Number of gram equivalents of H2SO4= Normality × Volume in L
=0.1×0.2=0.02
Number of gram equivalents of NaOH = Normality × Volume in L
=0.01×0.3=0.003
0.003 gram equivalents of NaOH will neutralize 0.003 gram equivalents of H2SO4.
Hence, the number of gram equivalents of H2SO4 in 500 mL of the solution after neutralisation = 0.02 - 0.003
= 0.017
Hence, the number of gram equivalents of H+= 0.017
Normality of H+=Number of gram equivalentsVolume of solution in L

Normality of H+= 0.0170.5=0.034 N

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