24. When equilibrium is established in a galvanic or electrochemical cell Ecell=0, Why?

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2 F e_{(a q)}^{+ 3} + Z n_{(s)} \to Z n_{(a q)}^{+ 2} + 2 F e_{(a q)}^{+ 2}

F e^{+ 2}

2 {F e}_{(a q)}^{+ 3} + {Z n}_{(s)} \to {Z n}_{(a q)}^{+ 2} + 2 {F e}_{(a q)}^{+ 2}

{F e}^{+ 2}

M | M^{+} | | X | X^{-}

E_{M^{+} / M}^{0} = 0.44 V

E_{X / X^{-}}^{0} = 0.33 V

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