No of moles of Na+ = 2× no of mole of Na2CO3 and no of moles of CO3-2= no of mole of Na2CO3. Here no of moles of Na2CO3 is 25/106.
So molarity of Na+= 2× (25/106)×1000/250= 200/106= 100/53.
Similarly molarity of CO3-2= (25/106)×1000/250= 100/106= 50/53.